To learn Tom Jobim - Desafinado chords, anchor your practice on these foundational sequence of chords - Bm, G, Am, Db, Fm, Cm, F, G, Bb, E, Eb and D. A strategic approach would be to train at 72 BPM initially, and then accelerate to the song's tempo of 144. To match your vocal range and chord inclination, adjust the capo in line with the key: C Minor.